Search results for "Callitrisic acid"

showing 2 items of 2 documents

A Short and Improved Synthesis of the Antiprotozoal Abietane Diterpenoid (–)-Sugikurojin A

2016

An efficient and straightforward semisynthesis of the antiprotozoal abietane diterpenoid (–)-sugikurojin A, starting from the readily available methyl ester of callitrisic acid (4-epi-dehydroabietic acid­) isolated from sandarac resin, is reported. This optimized semi­synthetic route provides a convenient source of the antiprotozoal compound, in four steps from methyl callitrisate in 50% overall yield, for further biological studies.

0301 basic medicineBiological studiesChemistrymedicine.drug_classTerpenoidsAcylation030106 microbiologyOrganic ChemistrySandaracSemisynthesisCatalysisTerpenoidCallitrisic acidAcylation03 medical and health scienceschemistry.chemical_compoundYield (chemistry)AbietanesAntiprotozoalmedicineOrganic chemistrySemisynthesisAbietane
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Biological Profiling of Semisynthetic C19-Functionalized Ferruginol and Sugiol Analogues

2021

[EN] The abietane-type diterpenoids are significant bioactive compounds exhibiting a varied range of pharmacological properties. In this study, the first synthesis and biological investigation of the new abietane-diterpenoid (+)-4-epi-liquiditerpenoid acid (8a) together with several of its analogs are reported. The compounds were generated from the readily available methyl callitrisate (7), which was obtained from callitrisic acid present in Moroccan Sandarac resin. A biological evaluation was conducted to determine the effects of the different functional groups present in these molecules, providing basic structure-activity relationship (SAR) elements. In particular, the ferruginol and sugi…

Microbiology (medical)Pharmacology.KetoneStereochemistryCarboxylic acidFarmacología.Antiproliferative activity01 natural sciencesBiochemistryMicrobiologyArticleAntimalarial activityHeLachemistry.chemical_compoundDiterpenoidMoiety03.- Garantizar una vida saludable y promover el bienestar para todos y todas en todas las edadesPharmacology (medical)General Pharmacology Toxicology and PharmaceuticsAbietanechemistry.chemical_classificationMalaria - Chemotherapy.biology010405 organic chemistryChemistrylcsh:RM1-950Sandaracbiology.organism_classificationGABA<sub>A</sub> receptor modulatorsTerpenoidCallitrisic acid0104 chemical sciencesFerruginol010404 medicinal & biomolecular chemistrylcsh:Therapeutics. PharmacologyInfectious DiseasesPaludismo - Farmacoterapia.AbietaneGABAA receptor modulators
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